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First Law of Thermodynamics

thermodynamics_engrzSo far, we have considered various forms of energy such as heat Q, work W, and total energy E individually, and no attempt is made to relate them to each other during a process. The first law of thermodynamics, also known as the conservation of energy principle, provides a sound basis for studying the relationships among the various forms of energy and energy interactions. Based on experimental observations, the first law of thermodynamics states that energy can be neither created nor destroyed during a process; it can only change forms. Therefore, every bit of energy should be accounted for during a process.
We all know that a rock at some elevation possesses some potential energy, and part of this potential energy is converted to kinetic energy as the rock falls (Fig. 2–37). Experimental data show that the decrease in potential energy (mg z) exactly equals the increase in kinetic energy when the air resistance is negligible, thus confirming the conservation of energy principle for mechanical energy.
Consider a system undergoing a series of adiabatic processes from a specified state 1 to another specified state 2. Being adiabatic, these processes obviously cannot involve any heat transfer, but they may involve several kinds of work interactions. Careful measurements during these experiments indicate the following: For all adiabatic processes between two specified states of a closed system, the net work done is the same regardless of the nature of the closed system and the details of the process. Considering
that there are an infinite number of ways to perform work interactions under adiabatic conditions, this statement appears to be very powerful, with a potential for far-reaching implications. This statement, which is largely based on the experiments of Joule in the first half of the nineteenth century, cannot be drawn from any other known physical principle and is recognized as a fundamental principle. This principle is called the first law of thermodynamics or just the first law.
thermodynamics_engrzA major consequence of the first law is the existence and the definition of the property total energy E. Considering that the net work is the same for all adiabatic processes of a closed system between two specified states, the value of the net work must depend on the end states of the system only, and thus it must correspond to a change in a property of the system. This prop- erty is the total energy. Note that the first law makes no reference to the value of the total energy of a closed system at a state. It simply states that the change in the total energy during an adiabatic process must be equal to the net work done. Therefore, any convenient arbitrary value can be assigned to total energy at a specified state to serve as a reference point.
Implicit in the first law statement is the conservation of energy. Although the essence of the first law is the existence of the property total energy, the first law is often viewed as a statement of the conservation of energy principle. Next we develop the first law or the conservation of energy relation with the help of some familiar examples using intuitive arguments.
First, we consider some processes that involve heat transfer but no work interactions. The potato baked in the oven is a good example for this case (Fig. 2–38). As a result of heat transfer to the potato, the energy of the potato will increase. If we disregard any mass transfer (moisture loss from the potato), the increase in the total energy of the potato becomes equal to the amount of heat transfer. That is, if 5 kJ of heat is transferred to the potato, the energy increase of the potato will also be 5 kJ.
As another example, consider the heating of water in a pan on top of a range (Fig. 2–39). If 15 kJ of heat is transferred to the water from the heating element and 3 kJ of it is lost from the water to the surrounding air, the increase in energy of the water will be equal to the net heat transfer to water, which is 12 kJ.
Now consider a well-insulated (i.e., adiabatic) room heated by an electric heater as our system (Fig. 2–40). As a result of electrical work done, the energy of the system will increase. Since the system is adiabatic and cannot have any heat transfer to or from the surroundings (Q = 0), the conservation of energy principle dictates that the electrical work done on the system must equal the increase in energy of the system.
Next, let us replace the electric heater with a paddle wheel (Fig. 2–41). As a result of the stirring process, the energy of the system will increase. Again, since there is no heat interaction between the system and its surroundings (Q = 0), the shaft work done on the system must show up as an increase in the energy of the system.
Many of you have probably noticed that the temperature of air rises when it is compressed (Fig. 2–42). This is because energy is transferred to the air in the form of boundary work. In the absence of any heat transfer (Q = 0), the entire boundary work will be stored in the air as part of its total energy. The conservation of energy principle again requires that the increase in the energy of the system be equal to the boundary work done on the system.

 thermodynamics_engrzWe can extend these discussions to systems that involve various heat and work interactions simultaneously. For example, if a system gains 12 kJ of heat during a process while 6 kJ of work is done on it, the increase in the energy of the system during that process is 18 kJ (Fig. 2–43). That is, the change in the energy of a system during a process is simply equal to the net energy transfer to (or from) the system.

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Reference: Thermodynamics – An Engineering Approach
5th Edition
by: Yunus A. Cengel and Michale A. Boles

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